TA Instruments

25% SID 75% PCHINA-0036f

06/05/2022 10:36:05 a. m.

Sample name	25% SID 75% PCHINA
Sample notes	 
Experiment notes	
Operator	
Sample density	1,000 g/cm^3
Results file name	25% SID 75% PCHINA
Run number	36 
Results directory	C:\Ta\Data\Ar1500\Ar1500\DIEGO ROA
Experiment was run on	06/05/2022 10:36:05 a. m.

Procedure name	Flow procedure
Procedure notes	

Step name	Conditioning Step 1
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	No
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Stepped flow step 1
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000E-3 1/s
End controlled variable	shear rate 0,01000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 2
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,01000 1/s
End controlled variable	shear rate 0,1000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 3
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,1000 1/s
End controlled variable	shear rate 1,000 1/s
Ramp mode	log 
Points per decade	5 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 4
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000 1/s
End controlled variable	shear rate 100,0 1/s
Ramp mode	log 
Points per decade	8 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Conditioning Step 2
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	Yes
Pre-shear variable	10,00 1/s
Pre-shear duration	0:00:10 hh:mm:ss
Motor mode	auto 
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Temperature ramp step 1
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	25,0 C
End temperature	90,0 C
Wait for start temperature	Yes
Ramp rate	10,00 C/min
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Temperature ramp step 2
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	90,0 C
End temperature	90,0 C
Wait for start temperature	No
Ramp duration	0:05:00 hh:mm:ss
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Temperature ramp step 3
Step notes	
Perform step	Yes
Ramp type	Temperature ramp
Start temperature	90,0 C
End temperature	25,0 C
Wait for start temperature	No
Ramp rate	10,00 C/min
Delay time	0:00:09 hh:mm:ss
Controlled variable	shear rate 10,00 1/s
Motor mode	auto 

Step name	Conditioning Step 3
Step notes	
Perform step	Yes
Initial temperature	25,0 C
Wait for correct temperature	Yes
Do set temperature	Yes
Perform pre-shear	Yes
Pre-shear variable	1,000 1/s
Pre-shear duration	0:00:10 hh:mm:ss
Motor mode	auto 
Perform equilibration	Yes
Equilibration duration	0:02:00 hh:mm:ss
Wait for zero velocity	No
Purge gas only	No

Step name	Stepped flow step 5
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000E-3 1/s
End controlled variable	shear rate 0,01000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 6
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,01000 1/s
End controlled variable	shear rate 0,1000 1/s
Ramp mode	log 
Points per decade	3 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 7
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 0,1000 1/s
End controlled variable	shear rate 1,000 1/s
Ramp mode	log 
Points per decade	5 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Stepped flow step 8
Step notes	
Perform step	Yes
Ramp type	Stepped flow
Start controlled variable	shear rate 1,000 1/s
End controlled variable	shear rate 100,0 1/s
Ramp mode	log 
Points per decade	8 
Temperature	25,0 C
Wait for temperature	No
Constant time	0:00:10 hh:mm:ss
Average last x seconds	0:00:05 hh:mm:ss
Motor mode	auto 
Integer rotation averaging	No

Step name	Post-Experiment Step
Step notes	
Perform step	Yes
Do set temperature	No
Set temperature system idle	No

Geometry name	Starch cell
Geometry notes	Starch cell
Geometry material	High temperature
gap	5500 micro m
Calibration factor	10800 
Gap offset	0 micro m
Geometry inertia	2,226 micro N.m.s^2
Shear rate factor	1,000 
Shear stress factor	10800 1/m^3
Measurement system factor	10800 1/m^3
Fluid density factor	1,000E-15 m^5
Normal force factor	1,000 1/m^2
Backoff distance	1,25E5 micro m

Gap zero mode	Standard
Sample compression	none 
Compression distance	1000,0 micro m
Compression velocity	100,0 micro m/s
Fine velocity	1000,0 micro m/s
Coarse velocity	3000,0 micro m/s
Other velocity	3000,0 micro m/s
Current temperature system	Starch cell
Temperature control	Enabled 
Purge gas only	No
Temperature calibration	Peltier plate - 0 micro m/C
	Water bath - 0 micro m/C
	Torsion oven - plate - 0 micro m/C
	Torsion oven - solid sample - 0 micro m/C
	Peltier concentric cylinders - 0 micro m/C
	None - 0 micro m/C
	Stress relaxation - 0 micro m/C
	Current temperature system - 0 micro m/C
Cooling water temperature	5,0 C
Cooling water range	15,0 C
Bearing friction correction	Yes
Bearing friction	1,222 micro N.m/(rad/s)
Bearing offset	0 micro N.m
Temperature system span and offset	Peltier plate - span 1,0000 , offset 0 C
	Water bath - span 1,0000 , offset 0 C
	Torsion oven - plate - span 1,0000 , offset 0 C
	Torsion oven - solid sample - span 1,0000 , offset 0 C
	Peltier concentric cylinders - span 1,0000 , offset 0 C
	None - span 1,0000 , offset 0 C
	Stress relaxation - span 1,0000 , offset 0 C
	Current temperature system - span 1,0000 , offset 0 C
Bearing mapping type	fast 
Number of mapping iterations	1
Instrument type (MType)	AR1500ex
Firmware version	  8.29  27/10/09
Configuration version (CnfVer)	301
Parameter version (PrmVer)	301
PCB Number	*NOT_SET*
IP address	172.23.191.2
Software version	V5.8.2
Windows version	Windows XP 6.2
Instrument inertia	15,97 micro N.m.s^2
Auto increment run number	Yes
Prompt for file name at start of run	Yes
Auto save results file	Yes
Results file storage	Consecutive steps of same type to 1 file 
Temperature tolerance	0,2 C
Temperature duration	0:00:10 hh:mm:ss
Wait for temperature even if OK	Yes
Gap tolerance	4 micro m
Gap duration	0:00:02 hh:mm:ss
Override wait for gap	No
Velocity tolerance	0,1000 rad/s
Zero speed after pre-shear	Leave as is 
Zero normal force before run	No
Zero timer before run	Before pre-shear 
Non-equilibrium minimum velocity	3,000E-4 rad/s
Zero strain at the start of each flow step	Yes
Inertia correction	No
Collect negative shear rate data if stress is positive	Yes
Collect all points	No
Display flow point graph during run	Yes
Store flow point graph with results	Yes
Store images to the results for flow steps	No
Creep zero displacement	Yes
Store images to the results for creep steps	No
Standard creep image store frequency	10 s
Repeated creep image store frequency in repeats	10 
Display oscillation waveform graph during run	Yes
Store oscillation waveform graph with results	Yes
Display strain control tries during run	Yes
Store strain control tries with results	Yes
Store images to the results for oscillation steps	No
Stress relaxation zero displacement	Yes
Store images to the results for stress relaxation steps	No
Flow torque limit	10,00 micro N.m
Flow velocity limit	1,000E-3 rad/s
Oscillation torque limit	5,00 micro N.m
Oscillation displacement limit	1,00E-5 rad
Oscillation raw phase limit	170,0 degrees
Oscillation minimum normal force limit	0 N
Oscillation maximum normal force limit	0 N
Flow velocity tolerance	5,00 %
Oscillation torque tolerance	1,00 %
Oscillation displacement tolerance	5,00 %
Oscillation velocity tolerance	5,00 %
Temperature tolerance	1,0 C

Stepped flow step 1

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,02097	9,916E-4	21,15	9,9220	25,0	0
0,04629	2,154E-3	21,49	19,969	25,0	0
0,08020	4,641E-3	17,28	30,094	25,0	0
0,1374	9,998E-3	13,75	40,157	25,0	0

Stepped flow step 2

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,1683	0,01000	16,83	9,8910	25,0	0
0,2370	0,02154	11,00	20,000	25,0	0
0,3279	0,04641	7,065	30,094	25,0	0
0,4203	0,1000	4,203	40,141	25,0	0
0,4162	0,1000	4,162	50,219	25,0	0

Stepped flow step 3

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,3492	0,1000	3,492	9,9840	25,0	0
0,3198	0,1585	2,018	20,031	25,0	0
0,2709	0,2512	1,079	30,093	25,0	0
0,2315	0,3981	0,5816	40,140	25,0	0
0,2306	0,6310	0,3654	50,203	25,0	0
0,2113	1,000	0,2113	60,265	25,0	0

Stepped flow step 4

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,1958	1,000	0,1958	9,9840	25,0	0
0,1980	1,334	0,1485	20,016	25,0	0
0,1947	1,778	0,1095	30,047	25,0	0
0,1959	2,371	0,08262	40,141	25,0	0
0,1997	3,162	0,06314	50,234	25,0	0
0,2042	4,217	0,04843	60,312	25,0	0
0,1688	5,623	0,03002	70,391	25,0	0
0,1802	7,499	0,02402	80,719	25,0	0
0,2615	10,00	0,02615	90,797	25,0	0
0,4019	13,34	0,03014	100,86	25,0	0
0,7167	17,78	0,04031	110,91	25,0	0
1,013	23,71	0,04271	121,00	25,0	0
1,558	31,62	0,04928	131,05	25,0	0
2,100	42,17	0,04981	141,13	25,0	0
3,337	56,23	0,05935	151,17	25,0	0
5,045	74,99	0,06727	161,25	25,0	0
7,454	100,0	0,07455	171,34	25,0	0

Temperature ramp step 1

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,2831	10,00	0,02831	8,9920	25,0	0
0,2799	10,00	0,02799	18,004	25,5	0
0,2781	10,00	0,02781	26,996	26,6	0
0,2756	10,00	0,02756	36,012	28,1	0
0,2728	10,00	0,02728	45,004	29,8	0
0,2705	10,00	0,02705	54,004	31,5	0
0,2662	10,00	0,02662	62,992	33,2	0
0,2652	10,00	0,02652	72,000	34,9	0
0,2638	10,00	0,02638	80,996	36,5	0
0,2624	10,00	0,02624	89,996	38,1	0
0,2628	10,00	0,02628	99,004	39,7	0
0,2627	10,00	0,02627	108,00	41,2	0
0,2663	10,00	0,02663	117,01	42,8	0
0,2662	10,00	0,02662	126,01	44,4	0
0,2678	10,00	0,02678	135,00	45,9	0
0,2668	10,00	0,02668	143,99	47,3	0
0,2693	10,00	0,02693	152,99	48,9	0
0,2729	10,00	0,02729	161,99	50,4	0
0,2734	10,00	0,02734	170,99	51,8	0
0,2732	10,00	0,02732	179,99	53,4	0
0,2650	10,00	0,02650	188,99	54,8	0
0,2641	10,00	0,02641	198,00	56,4	0
0,2689	10,00	0,02689	206,99	57,8	0
0,2694	10,00	0,02694	215,99	59,3	0
0,2724	10,00	0,02724	225,00	60,8	0
0,2828	10,00	0,02828	233,99	62,3	0
0,2881	10,00	0,02881	242,99	63,9	0
0,2954	10,00	0,02954	252,00	65,4	0
0,3048	10,00	0,03048	261,00	66,9	0
0,3167	10,00	0,03167	270,00	68,4	0
0,3346	10,00	0,03346	279,00	69,9	0
0,3554	10,00	0,03554	288,01	71,4	0
0,3954	10,00	0,03954	297,00	72,9	0
0,4830	9,999	0,04831	306,00	74,4	0
0,7444	9,999	0,07444	315,00	75,9	0
1,560	9,999	0,1560	324,00	77,5	0
3,112	9,999	0,3112	333,00	79,1	0
5,890	9,999	0,5891	342,00	80,6	0
10,44	9,999	1,044	350,99	81,9	0
15,99	10,00	1,599	360,00	83,3	0
21,65	10,00	2,165	369,01	84,7	0

Temperature ramp step 2

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

27,07	10,00	2,707	9,0040	86,5	0
29,47	10,00	2,947	18,012	88,9	0
31,66	10,00	3,166	27,000	90,2	0
30,62	10,00	3,062	36,000	90,7	0
29,29	10,00	2,929	45,004	90,9	0
28,04	10,00	2,804	54,012	90,9	0
26,84	10,00	2,684	62,996	90,8	0
25,86	10,00	2,586	71,996	90,8	0
25,04	10,00	2,504	80,996	90,7	0
24,44	10,00	2,443	90,008	90,6	0
23,89	10,00	2,389	98,996	90,4	0
23,39	9,999	2,339	108,01	90,3	0
23,05	10,00	2,305	117,00	90,3	0
22,65	10,00	2,265	126,01	90,2	0
22,37	10,00	2,236	135,00	90,1	0
22,06	10,00	2,206	144,01	90,1	0
21,76	9,999	2,176	153,00	90,1	0
21,52	10,00	2,152	162,00	90,1	0
21,38	10,00	2,138	171,00	90,0	0
21,07	10,00	2,107	180,00	90,0	0
20,97	10,00	2,097	189,01	90,0	0
20,62	10,00	2,062	198,00	90,0	0
20,47	10,00	2,047	207,00	90,0	0
20,32	10,00	2,032	216,00	90,0	0
20,08	10,00	2,008	225,00	90,0	0
19,83	10,00	1,983	233,99	90,0	0
19,70	10,00	1,970	243,00	90,0	0
19,42	10,00	1,942	252,00	90,0	0
19,23	10,00	1,923	261,00	90,0	0
19,04	10,00	1,904	270,01	90,0	0
18,91	10,00	1,891	279,00	90,0	0

Temperature ramp step 3

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

18,62	10,00	1,862	9,0000	90,0	0
18,59	10,00	1,859	18,004	89,5	0
18,56	9,999	1,856	27,020	86,0	0
18,41	10,00	1,840	36,008	85,1	0
18,37	10,00	1,837	45,020	84,6	0
18,33	10,00	1,833	54,004	83,6	0
18,41	10,00	1,841	63,012	81,2	0
18,49	10,00	1,849	72,000	79,7	0
18,45	10,00	1,845	81,016	78,9	0
18,69	10,00	1,869	90,000	77,0	0
18,74	10,00	1,874	99,008	75,1	0
18,88	10,00	1,888	108,00	74,3	0
19,15	10,00	1,915	117,00	72,3	0
19,39	10,00	1,939	126,00	70,7	0
19,51	10,00	1,951	135,00	69,9	0
19,77	10,00	1,977	144,00	67,4	0
20,09	9,999	2,009	153,01	66,5	0
20,35	10,00	2,035	162,00	64,8	0
20,64	9,999	2,064	171,02	63,0	0
20,93	9,999	2,093	180,01	62,2	0
21,46	9,999	2,147	189,00	59,9	0
21,88	10,00	2,188	198,02	59,0	0
22,38	9,999	2,238	207,01	57,1	0
22,86	10,00	2,286	216,00	55,6	0
23,39	10,00	2,339	225,00	54,6	0
23,93	10,00	2,393	234,01	52,5	0
24,44	10,00	2,443	243,00	51,5	0
25,03	10,00	2,503	252,00	49,6	0
25,60	10,00	2,560	261,02	48,3	0
26,34	9,999	2,634	270,01	46,8	0
27,02	9,999	2,702	279,01	45,2	0
27,64	10,00	2,764	288,00	43,8	0
28,39	9,999	2,839	297,00	42,2	0
28,99	10,00	2,899	306,01	40,7	0
29,62	10,00	2,962	315,01	39,3	0
30,48	9,999	3,048	323,99	37,7	0
31,16	10,00	3,117	333,00	36,3	0
31,92	10,00	3,192	342,00	34,8	0
32,81	10,00	3,281	351,00	33,3	0
33,80	10,00	3,380	360,01	31,9	0
34,77	9,999	3,477	369,00	30,4	0

Stepped flow step 5

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

0,3106	1,004E-3	309,3	9,9060	24,9	0
0,7743	2,153E-3	359,6	19,968	25,0	0
1,437	4,640E-3	309,7	30,031	25,0	0
2,482	9,998E-3	248,2	40,109	24,9	0

Stepped flow step 6

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

3,004	9,999E-3	300,4	9,9210	24,9	0
4,315	0,02154	200,3	20,046	25,0	0
6,102	0,04642	131,5	30,156	25,0	0
8,254	0,1000	82,54	40,250	24,9	0
8,280	0,1000	82,80	50,250	24,9	0

Stepped flow step 7

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

8,367	0,1000	83,67	9,9380	25,0	0
9,928	0,1585	62,64	20,000	25,1	0
11,79	0,2512	46,94	30,094	24,9	0
13,93	0,3981	35,00	40,234	24,9	0
16,58	0,6310	26,29	50,344	25,0	0
19,94	1,000	19,94	60,391	25,1	0

Stepped flow step 8

shear stress	shear rate	viscosity	time	temperature	normal stress
Pa	1/s	Pa.s	s	C	Pa

19,47	1,000	19,47	9,9380	25,0	0
21,95	1,334	16,46	20,032	24,9	0
24,82	1,778	13,96	30,125	25,0	0
28,13	2,371	11,86	40,188	25,1	0
31,93	3,162	10,10	50,297	25,0	0
36,40	4,217	8,632	60,344	25,0	0
41,51	5,623	7,381	70,422	25,0	0
47,29	7,499	6,306	80,469	25,1	0
53,78	10,00	5,378	90,516	25,0	0
60,38	13,34	4,527	100,55	24,9	0
67,81	17,78	3,813	110,63	25,0	0
74,33	23,71	3,135	120,69	25,0	0
79,18	31,62	2,504	130,83	25,0	0
87,54	42,17	2,076	140,83	25,0	0
95,10	56,23	1,691	150,92	25,0	0
103,0	74,99	1,374	160,99	25,0	0
109,8	100,0	1,098	171,09	25,0	0

